Volume 31, Issue 16
Isocyclic Compounds
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ChemInform Abstract: Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction.

Yuan-Yong Yan

Yuan-Yong Yan

Dep. Chem., Ohio State Univ., Columbus, OH 43210, USA

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T. V. RajanBabu

T. V. RajanBabu

Dep. Chem., Ohio State Univ., Columbus, OH 43210, USA

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First published: 09 June 2010

Abstract

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ChemInform Abstract

High enantioselectivities for the Pd-catalyzed asymmetric allylation of dimethyl malonate are achieved in the presence of chiral phospholane ligands derived from D-mannitol.

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