ChemInform Abstract: Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction.
Abstract
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ChemInform Abstract
High enantioselectivities for the Pd-catalyzed asymmetric allylation of dimethyl malonate are achieved in the presence of chiral phospholane ligands derived from D-mannitol.