Volume 31, Issue 16
Isocyclic Compounds
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ChemInform Abstract: The Reaction of Amines with an Electrogenerated Base. Improved Synthesis of Arylcarbamic Esters.

Marta Feroci

Marta Feroci

Dip. Chim., Ing. Chim. Mater., Univ. Stud., I-67040 Monteluco di Roio, L′ Aquaila, Italy

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Achille Inesi

Achille Inesi

Dip. Chim., Ing. Chim. Mater., Univ. Stud., I-67040 Monteluco di Roio, L′ Aquaila, Italy

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Leucio Rossi

Leucio Rossi

Dip. Chim., Ing. Chim. Mater., Univ. Stud., I-67040 Monteluco di Roio, L′ Aquaila, Italy

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Electrolysis of 2-pyrrolidinone/tetraethylammonium perchlorate generates a solution of 2-pyrrolidinone amide base which is used as reagent for the synthesis of carbamates (IV) from amines (I), carbon dioxide and ethyl iodide.

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