ChemInform Abstract: The Reaction of Amines with an Electrogenerated Base. Improved Synthesis of Arylcarbamic Esters.
Abstract
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ChemInform Abstract
Electrolysis of 2-pyrrolidinone/tetraethylammonium perchlorate generates a solution of 2-pyrrolidinone amide base which is used as reagent for the synthesis of carbamates (IV) from amines (I), carbon dioxide and ethyl iodide.