Preparative Organic Chemistry
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ChemInform Abstract: Diisopropoxyaluminum Trifluoroacetate: A New Promoter for Aminolysis of Epoxides.
First published: 09 June 2010
Abstract
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ChemInform Abstract
The aminolysis of cyclohexene oxide (I) with DIPAT as promotor gives exclusively the corresponding trans-1,2-aminoalcohols such as (III). The same reaction with styrene oxide (IV) gives two regioisomers such as (V) and (VI).
