Volume 31, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Photochemical Oxidation of 4H-Seleno(thio)pyrans.

B. I. Drevko

B. I. Drevko

Chernyshevskii Saratov State Univ., Saratov 410026, Russia

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L. A. Fomenko

L. A. Fomenko

Chernyshevskii Saratov State Univ., Saratov 410026, Russia

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M. A. Suchkov

M. A. Suchkov

Chernyshevskii Saratov State Univ., Saratov 410026, Russia

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V. G. Kharchenko

V. G. Kharchenko

Chernyshevskii Saratov State Univ., Saratov 410026, Russia

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Oxidation of chalcogenopyrans (I) and (III) into the corresponding heteroaromatic cations is achieved on UV-irradiation in the presence of CBr4. The reaction occurs via a free radical chain mechanism.

chemical structure image

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