Volume 31, Issue 12
Natural Products
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ChemInform Abstract: A Simple Synthesis of (-)-(R)-Ipsdienol and (-)-(S)-Ipsenol.

Karine Draillard

Karine Draillard

Lab. Synth. Org., CNRS, Fac. Sci. Tech., Univ. Nantes, F-44322 Nantes, Fr.

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Jacques Lebreton

Jacques Lebreton

Lab. Synth. Org., CNRS, Fac. Sci. Tech., Univ. Nantes, F-44322 Nantes, Fr.

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Jean Villieras

Jean Villieras

Lab. Synth. Org., CNRS, Fac. Sci. Tech., Univ. Nantes, F-44322 Nantes, Fr.

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First published: 09 June 2010

Abstract

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ChemInform Abstract

The synthesis of the title compounds (VIa) and (VIb) is achieved via asymmetric allylboration and one-pot reduction/methylenation of the lactones (IV).

chemical structure image

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