Preparative Organic Chemistry
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ChemInform Abstract: New Method for Preparation of α-Substituted Acrylonitrile Derivatives.
First published: 09 June 2010
Abstract
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ChemInform Abstract
Quaternization of the nitrogen atom of both dimethylamino groups in α-substituted dimethylamino hydrazones (I) followed by Hoffman decomposition of the resulting diiodides (II) provides a novel and convenient route for the synthesis of α-substituted acrylonitrile derivatives (III) (5 examples).
