Volume 31, Issue 12
Preparative Organic Chemistry
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ChemInform Abstract: 4,4-Dimethyl-4,5-dihydro-1,2-dithiolo[3,4-c]quinoline-1-thiones in 1,3-Dipolar Cycloaddition Reactions with Acetylenic Dipolarophiles.

Kh. S. Shikhaliev

Kh. S. Shikhaliev

Voronezh State Univ., Voronezh 394693, Russia

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S. M. Medvedeva

S. M. Medvedeva

Voronezh State Univ., Voronezh 394693, Russia

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G. I. Ermolova

G. I. Ermolova

Voronezh State Univ., Voronezh 394693, Russia

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G. V. Shatalov

G. V. Shatalov

Voronezh State Univ., Voronezh 394693, Russia

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Reaction of the title quinolinethiones (I) with equimolar amounts of acetylenic dipolarophiles provides dithiolylidenequinolinethiones in good yields. Reaction of compounds (I) with two-fold excess of acetylenic dipolarophiles gives 1:2 adducts with spiro structure (IV).

chemical structure image

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