Volume 31, Issue 12
Physical Inorganic Chemistry
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ChemInform Abstract: K[ZnBP2O8] and A[ZnBP2O8] (A: NH4+, Rb+, Cs+): Zincoborophosphates as a New Class of Compounds with Tetrahedral Framework Structures.

Ruediger Kniep

Ruediger Kniep

Eduard-Zintl-Inst., TH Darmstadt, D-64289 Darmstadt, Germany

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Gerd Schaefer

Gerd Schaefer

Eduard-Zintl-Inst., TH Darmstadt, D-64289 Darmstadt, Germany

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Holger Engelhardt

Holger Engelhardt

Eduard-Zintl-Inst., TH Darmstadt, D-64289 Darmstadt, Germany

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Insan Boy

Insan Boy

Eduard-Zintl-Inst., TH Darmstadt, D-64289 Darmstadt, Germany

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Title compound (IV) crystallizes in the monoclinic system (space group C2/c, Z = 8), while compounds (VII) and (X) are triclinic (space group Pequation image, Z = 2) as determined by single crystal X-ray diffraction. The structures of all these compounds are based on four-rings which contain corner-sharing borate, phosphate, and zincate tetrahedra.

chemical structure image

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