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ChemInform Abstract: Thioamide Derivatives of Cannabinoids. A Study of the Influence of the Thioamide Function on Regiochemistry in the Synthesis of Thioamide Cannabinoids from 2,4-Dihydroxybenzothioamides.
First published: 11 June 2010
Abstract
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ChemInform Abstract
Several thiocarbamoyl derivatives of cannabinoids [cf. (V) and (VIII)] are obtained in the collidine-catalyzed condensation of readily achieved dihydroxybenzothiamides (III) with citral (IV) and citronellal (VII). The experimental results and theoretical (FMO theory) considerations make it possible to advance the reaction mechanism.
