Volume 31, Issue 5
Organoelement Compounds
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ChemInform Abstract: (Benzamidomethyl)dimethylsilanol Hydrochloride. Oxonium Structure and Intra- and Intermolecular Coordination Interactions.

S. A. Pogozhikh

S. A. Pogozhikh

Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia

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O. A. Zamyshlyaeva

O. A. Zamyshlyaeva

Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia

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E. P. Kramarova

E. P. Kramarova

Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia

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M. Yu. Antipin

M. Yu. Antipin

Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia

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Yu. E. Ovchinnikov

Yu. E. Ovchinnikov

Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia

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Yu. I. Baukov

Yu. I. Baukov

Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia

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First published: 11 June 2010

Abstract

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ChemInform Abstract

Long-time storage of easily available silyl chloride (II) under conditions not excluding atmospheric moisture results in the formation of the crystalline title silanol (III), which appears to be a cation-anionic H-associate with five-coordinate silicon atom.

chemical structure image

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