Volume 31, Issue 5
Preparative Organic Chemistry
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ChemInform Abstract: Mn—Trimethyltriazacyclononane/Ascorbic Acid: A Remarkably Efficient Catalyst for the Epoxidation of Olefins and the Oxidation of Alcohols with Hydrogen Peroxide.

Albrecht Berkessel

Albrecht Berkessel

Inst. Org. Chem., Univ. Koeln, D-50939 Koeln, Germany

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Christoph A. Sklorz

Christoph A. Sklorz

Inst. Org. Chem., Univ. Koeln, D-50939 Koeln, Germany

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First published: 11 June 2010

Abstract

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ChemInform Abstract

A system comprised of Mn2+, 1,4,7-trimethyl-1,4,7-triazacyclononane, and the sodium salt of ascorbic acid efficiently catalyzes the oxidation of various substrates leading to epoxides, ketones, or carboxylic acids.

chemical structure image

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