Volume 31, Issue 5
Preparative Organic Chemistry
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ChemInform Abstract: Decomposition of 2-[4-(2-Chloro-1,1-dimethylethyl)phenyl]propan-2-yl Hydroperoxide Catalyzed by Sulfuric Acid.

F. Z. Galin

F. Z. Galin

Inst. Org. Chem., Ufa Res. Cent., Russ. Acad. Sci., Ufa 450054, Russia

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N. M. Andriyashina

N. M. Andriyashina

Inst. Org. Chem., Ufa Res. Cent., Russ. Acad. Sci., Ufa 450054, Russia

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T. V. Le

T. V. Le

Inst. Org. Chem., Ufa Res. Cent., Russ. Acad. Sci., Ufa 450054, Russia

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Yu. V. Tomilov

Yu. V. Tomilov

Inst. Org. Chem., Ufa Res. Cent., Russ. Acad. Sci., Ufa 450054, Russia

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V. V. Shereshovets

V. V. Shereshovets

Inst. Org. Chem., Ufa Res. Cent., Russ. Acad. Sci., Ufa 450054, Russia

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First published: 11 June 2010

Abstract

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ChemInform Abstract

The title reaction cleanly affords the corresponding phenol (II), which is a key intermediate in the synthesis of the synthetic pyrethroid ethopheneprox. The reaction kinetics is studied to optimize this process.

chemical structure image

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