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ChemInform Abstract: A Novel and Versatile Glycosyl Donor for the Preparation of Glycosides of N-Acetylneuraminic Acid.
First published: 20 June 2010
Abstract
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ChemInform Abstract
As part of a program connected with the synthesis of a hexasaccharide derived from the capsular polysaccharide of group B type III streptococcus, the conversion of thioglycoside (I) of Neu5Ac to the corresponding N-diacetyl compound (IV) is described. This transformation dramatically improves the glycosyl donor properties.
