Heterocyclic Compounds
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ChemInform Abstract: Optically Active Epoxy Diols by Titanium-Catalyzed Oxidation of Enantiomerically Enriched Hydroperoxy and Hydroxy Homoallylic Alcohols.
First published: 20 June 2010
Abstract
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ChemInform Abstract
The Ti-catalyzed epoxidation of the optically active hydroperoxy homoallylic alcohols (I) and the oxidation of the hydroxy homoallylic alcohols (VI) with 2,3-dimethyl-3-hydroperoxy-2-butanol afford in each case an erythro diol (II) or its enantiomer (VII) in high diastereoselectivity.
