Volume 29, Issue 11
Natural Products
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ChemInform Abstract: The Synthesis and Reactions of Some Novel Pyranoid 5,6-Glycals Derived from D-Fructose.

K. J. HALE

K. J. HALE

Christopher Ingold Lab., Dep. Chem., Univ. Coll., London WC1H 0AJ, UK

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S. MANAVIAZAR

S. MANAVIAZAR

Christopher Ingold Lab., Dep. Chem., Univ. Coll., London WC1H 0AJ, UK

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R. TUPPRASOOT

R. TUPPRASOOT

Christopher Ingold Lab., Dep. Chem., Univ. Coll., London WC1H 0AJ, UK

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First published: 23 June 2010

Abstract

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ChemInform Abstract

A new method to prepare pyranoid glycals like (III) via phenylselenation and subsequent oxidative elimination is described. The oxo derivative (IV) undergoes stereoselective functionalization at C-6.

chemical structure image

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