Volume 29, Issue 11
Preparative Organic Chemistry
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ChemInform Abstract: Catalytic Enantioselective Allylic Oxidation of Olefins with Copper(I) Catalysts and New Perester Oxidants.

M. B. ANDRUS

M. B. ANDRUS

Dep. Chem., Purdue Univ., West Lafayette, IN 47907, USA

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X. CHEN

X. CHEN

Dep. Chem., Purdue Univ., West Lafayette, IN 47907, USA

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First published: 23 June 2010

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

ChemInform Abstract

It offers an efficient method to prepare allylic benzoate esters like (III) and (V) with high enantioselectivity at reasonable rates. With copper catalysts prepared from CuPF6 higher enantioselectivity is observed than with catalysts generated from CuBr.

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