ChemInform Abstract: Catalytic Enantioselective Allylic Oxidation of Olefins with Copper(I) Catalysts and New Perester Oxidants.
Abstract
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ChemInform Abstract
It offers an efficient method to prepare allylic benzoate esters like (III) and (V) with high enantioselectivity at reasonable rates. With copper catalysts prepared from CuPF6 higher enantioselectivity is observed than with catalysts generated from CuBr.