Volume 29, Issue 11
Preparative Inorganic Chemistry
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ChemInform Abstract: Structure of Porous Aggregates of the Ammonium Salt of Dodecatungstophosphoric Acid, (NH4)3PW12O40: Unidirectionally Oriented Self-Assembly of Nanocrystallites.

T. ITO

T. ITO

Dep. Appl. Chem., Grad. Sch. Eng., Univ. Tokyo, Bunkyo, Tokyo 113, Japan

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K. INUMARU

K. INUMARU

Dep. Appl. Chem., Grad. Sch. Eng., Univ. Tokyo, Bunkyo, Tokyo 113, Japan

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M. MISONO

M. MISONO

Dep. Appl. Chem., Grad. Sch. Eng., Univ. Tokyo, Bunkyo, Tokyo 113, Japan

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First published: 23 June 2010

Abstract

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ChemInform Abstract

The title compound is precipitated at 368 K from aqueous solutions of H3PW12O40 and NH4HCO3 and crystallizes in the cubic system. The shape of formed aggregates changes from spherical to symmetric dodecahedral depending on the precipitation temperature.

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