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ChemInform Abstract: Enantioselective Total Synthesis of the (-)-(6R,11R,14S)-Isomer of Colletallol.
First published: 24 June 2010
Abstract
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ChemInform Abstract
The total synthesis of title compound (VII) is based on two consecutive Wittig reactions, the first one intermolecular and the second one intramolecular, instead of classical macrolactonizations. The strategy is flexible and should be useful for the preparation of further macrolide antibiotics.
