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ChemInform Abstract: Novel Synthetic Approach to 1α,24(R)-Dihydroxyvitamin D3 Using an Asymmetric Nitroaldol Reaction.
First published: 24 June 2010
Abstract
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ChemInform Abstract
Key step in the formal synthesis of vitamin D3 analogue (VI) is an asymmetric nitroaldol reaction using rare earth metal—alkali metal—BINOL complexes as chiral catalysts.
