Organoelement Compounds
Full Access
ChemInform Abstract: Reaction of Phosphaacetylenes tBuCP and 1-AdCP with (PhSe)2—XeF2: First Examples of Vicinal Bisselenenylation (at P and C) to Form Novel Phosphaalkenes.
First published: 24 June 2010
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract
The in situ generated PhSeF [(I)/XeF2] reacts with phosphaacetylenes (II) to give title products (III) in contrast to the reaction of PhSeCl (IV) with reactants (II) which undergo chloroselenenylation. The stereochemistry of compounds (III) is not unambiguously established but (E) configuration is assumed.
