ChemInform Abstract: Synthesis of Tetra- and Penta-Substituted Pyrrole Derivatives from Azazirconacyclopentene and Acyl Halide in the Presence of CuCl.
Abstract
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ChemInform Abstract
Pyrrole derivatives (IV) and (V) are synthesized from acyl halides ( III) and azazirconacyclopentene, prepared from complex (I) and alkyne ( II) in the presence of LiBHEt3, via transmetalation of zirconium to copper in a one-pot reaction.