Volume 28, Issue 50
Isocyclic Compounds
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ChemInform Abstract: Synthetic Usefulness of the Cobalt(I)-Mediated Ene Type Reaction for the Diastereoselective Construction of Bicyclo(n.3.0)derivatives.

J.-L. RENAUD

J.-L. RENAUD

Lab. Chim. Org. Synth., CNRS, Univ. P. et M. Curie, F-75252 Paris, Fr.

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M. PETIT

M. PETIT

Lab. Chim. Org. Synth., CNRS, Univ. P. et M. Curie, F-75252 Paris, Fr.

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C. AUBERT

C. AUBERT

Lab. Chim. Org. Synth., CNRS, Univ. P. et M. Curie, F-75252 Paris, Fr.

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M. MALACRIA

M. MALACRIA

Lab. Chim. Org. Synth., CNRS, Univ. P. et M. Curie, F-75252 Paris, Fr.

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First published: 02 August 2010

Abstract

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ChemInform Abstract

Cobalt-catalyzed photolytic cycloisomerization of cyclic β- ketoesters (II) (4 examples), yields the bicyclo(n.3.0)derivatives ( III) with total control of the stereochemistry.

chemical structure image

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