Preparative Organic Chemistry
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ChemInform Abstract: Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins.
First published: 02 August 2010
Abstract
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ChemInform Abstract
Photooxidation of cyclic trisubstituted olefins in the presence of NaN3 and copper(II) triflate gives keto nitriles (II) in good yield. No results are obtained in the case of the higher-membered disubstituted olefins (VIa) and (VIIIa).
