Volume 28, Issue 50
Preparative Organic Chemistry
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ChemInform Abstract: Amphiphilic Catalytic Allylating Reagent, Bis-π-allylpalladium Complex.

H. NAKAMURA

H. NAKAMURA

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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J.-G. SHIM

J.-G. SHIM

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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Y. YAMAMOTO

Y. YAMAMOTO

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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First published: 02 August 2010

Abstract

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ChemInform Abstract

Activated olefins such as (I) and (V) react with intermediary formed bis-π-allylpalladium as the first amphiphilic catalyst at the nucleophilic and electrophilic carbons to produce the double allylation products (IV) and (VI).

chemical structure image

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