Volume 28, Issue 15
Heterocyclic Compounds
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ChemInform Abstract: Reaction of α-Haloketones with ortho-Dihydroxy-2H-1-benzopyran-2- ones. Formation of α-Pyrano-1,5-benzodioxepines - A New Heterocyclic System.

A. PRASHANT

A. PRASHANT

Dep. Chem., Osmania Univ., Hyderabad 500 007, India

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G. D. KRUPADANAM

G. D. KRUPADANAM

Dep. Chem., Osmania Univ., Hyderabad 500 007, India

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R. R. GIL

R. R. GIL

Dep. Chem., Osmania Univ., Hyderabad 500 007, India

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L.-J. LIN

L.-J. LIN

Dep. Chem., Osmania Univ., Hyderabad 500 007, India

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G. A. CORDELL

G. A. CORDELL

Dep. Chem., Osmania Univ., Hyderabad 500 007, India

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First published: 04 August 2010

Abstract

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ChemInform Abstract

While the reaction of 7,8-dihydroxybenzopyranone (I) and its 4-methyl derivative (IV) with α-haloketones provides novel α-pyrano- 1,4-benzodioxepines, the 3-chlorinated benzopyranone (VIII) gives . alpha.-pyranobenzodioxane regioisomers under analogous conditions.

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