Volume 28, Issue 15
Heterocyclic Compounds
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ChemInform Abstract: Synthesis of Unsubstituted 4H,8H-Bisfurazano(3,4-b:3′,4′-e)pyrazine.

A. B. SHEREMETEV

A. B. SHEREMETEV

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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I. L. YUDIN

I. L. YUDIN

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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First published: 04 August 2010

Abstract

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ChemInform Abstract

The title compound (V) is synthesized by a novel four-step sequence starting from furazanopyrazine (I). Key step is the one-pot transformation of sulfilimine (IV) into (V) via an oxidation/tetrazole ring cleavage/nitrogen loss/ring closure/proton trapping sequence.

chemical structure image

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