Volume 28, Issue 15
Preparative Inorganic Chemistry
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ChemInform Abstract: Preparation of Hard Mesoporous Silica Spheres.

Q. HUO

Q. HUO

Dep. Chem., Univ. Calif., Santa Barbara, CA 93106, USA

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J. FENG

J. FENG

Dep. Chem., Univ. Calif., Santa Barbara, CA 93106, USA

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F. SCHUETH

F. SCHUETH

Dep. Chem., Univ. Calif., Santa Barbara, CA 93106, USA

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G. D. STUCKY

G. D. STUCKY

Dep. Chem., Univ. Calif., Santa Barbara, CA 93106, USA

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First published: 04 August 2010

Abstract

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ChemInform Abstract

Large transparent silica spheres are synthesized in a one-step procedure using oil-in-water emulsion chemistry using hydrophobic ( nBuO)4Si as Si source, cationic surfactants, and a base catalyst. The structure and size of pores depend on the pore-structure-directing CnMe3NCl (n = C12-18 alkyl) surfactant. By use of cetyltrimethylammonium bromide the spheres exhibit a BET surface area of 1100 m2/g which is comparable to those of zeolite-clay spheres.

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