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ChemInform Abstract: An Extremely Mild and General Method for the Construction of 1,2-trans- β-Glycosidic Linkages via Glycopyranosyl Diethyl Phosphites with Participating Groups at C-2.
First published: June 4, 1996
Abstract
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ChemInform Abstract
Tms-O-Tf-mediated glycosidation of glycosyl phosphites bearing participating groups such as benzoate (cf. (I)), phthalimido (cf. (IV)) or trichloroethyl carbamate (cf. (VII)) at C-2 constitutes an extremely mild and general method for the stereocontrolled construction of 1,2-trans-β-glycosidic linkages.
