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ChemInform Abstract: Synthesis of Carbocycles via Intramolecular Conjugate Additions: Total Syntheses of Axane Sesquiterpenoids.
First published: June 4, 1996
Abstract
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ChemInform Abstract
The key steps in the synthesis of the sesquiterpenoids (VIII)-(X) are highly diastereoselective intramolecular cyclization of the unsaturated ester (II) yielding the perhydroindan (III) and a series of cerium-mediated olefinations.
