Volume 27, Issue 23
Natural Products
Full Access

ChemInform Abstract: Total Synthesis of Forskolin. Part 1.

B. DELPECH

B. DELPECH

Unite Mixte, CNRS, Roussel Uclaf, F-93235 Romainville, Fr.

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D. CALVO

D. CALVO

Unite Mixte, CNRS, Roussel Uclaf, F-93235 Romainville, Fr.

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R. LETT

R. LETT

Unite Mixte, CNRS, Roussel Uclaf, F-93235 Romainville, Fr.

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First published: June 4, 1996

Abstract

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ChemInform Abstract

On route to a new total synthesis of forskolin the preparation of trans-fused enone (IV) as a key intermediate is reported. The key step is the intramolecular Diels-Alder reaction of the dienyne (II) to afford the tricyclic lactone (III).

chemical structure image

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