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ChemInform Abstract: A Practical Approach to Enantiomerically Pure cis-Epoxides. Synthesis of (+)-Disparlure.
First published: April 16, 1996
Abstract
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ChemInform Abstract
The title epoxide (VIII) is prepared in high optical purity (> 99.8% e. e.) via Sharpless asymmetric hydroxylation of the (E)-alkene (I) followed by Mitsunobu inversion of one hydroxyl group.
