Volume 27, Issue 16
Natural Products
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ChemInform Abstract: A New Access to Mori′s Intermediate for the Practical Synthesis of (-)- Periplanone-B.

S. HASHIMOTO

S. HASHIMOTO

Fac. Pharm. Sci., Teikyo Univ., Kanagawa 199-01, Japan

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Y. MIYAZAKI

Y. MIYAZAKI

Fac. Pharm. Sci., Teikyo Univ., Kanagawa 199-01, Japan

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M. SHIRO

M. SHIRO

Fac. Pharm. Sci., Teikyo Univ., Kanagawa 199-01, Japan

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S. IKEGAMI

S. IKEGAMI

Fac. Pharm. Sci., Teikyo Univ., Kanagawa 199-01, Japan

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First published: April 16, 1996

Abstract

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ChemInform Abstract

Mori′s key intermediate (XI) for the large-scale synthesis of (-)- periplanone-B (XII) is prepared in a new sequence from β-keto prenyl ester (IV).

chemical structure image

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