Volume 27, Issue 16
Organoelement Compounds
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ChemInform Abstract: Reduction of Phosphine Oxides, a Mild and Practical Synthesis of Secondary P-Ethynylphosphines.

J.-F. PILARD

J.-F. PILARD

Groupe Phys.-Chim. Struct., CNRS, Univ. Rennes I, F-35042 Rennes, Fr.

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G. BABA

G. BABA

Groupe Phys.-Chim. Struct., CNRS, Univ. Rennes I, F-35042 Rennes, Fr.

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A.-C. GAUMONT

A.-C. GAUMONT

Groupe Phys.-Chim. Struct., CNRS, Univ. Rennes I, F-35042 Rennes, Fr.

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J.-M. DENIS

J.-M. DENIS

Groupe Phys.-Chim. Struct., CNRS, Univ. Rennes I, F-35042 Rennes, Fr.

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First published: April 16, 1996

Abstract

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ChemInform Abstract

Reduction of the ethynyl phosphine oxides (I) with phenylsilane, a mixture of PhSiH3 and PhSiCl3 or pure PhSiHCl2 provides an efficient synthesis of the ethynylphosphines (II).

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