ChemInform Abstract: Synthesis of Highly Functionalized Thiophenes. 4-Aryl-3-carboxylate Derivatives.

G. M. COPPOLA,

G. M. COPPOLA

Dep. Atheroscler. Vasc. Biol., Preclin. Res., Sandoz Res. Inst., Sandoz Pharm. Corp., East Hanover, NJ 07936, USA

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R. E. DAMON,

R. E. DAMON

Dep. Atheroscler. Vasc. Biol., Preclin. Res., Sandoz Res. Inst., Sandoz Pharm. Corp., East Hanover, NJ 07936, USA

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H. YU,

H. YU

Dep. Atheroscler. Vasc. Biol., Preclin. Res., Sandoz Res. Inst., Sandoz Pharm. Corp., East Hanover, NJ 07936, USA

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G. M. COPPOLA,

G. M. COPPOLA

Dep. Atheroscler. Vasc. Biol., Preclin. Res., Sandoz Res. Inst., Sandoz Pharm. Corp., East Hanover, NJ 07936, USA

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R. E. DAMON,

R. E. DAMON

Dep. Atheroscler. Vasc. Biol., Preclin. Res., Sandoz Res. Inst., Sandoz Pharm. Corp., East Hanover, NJ 07936, USA

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H. YU,

H. YU

Dep. Atheroscler. Vasc. Biol., Preclin. Res., Sandoz Res. Inst., Sandoz Pharm. Corp., East Hanover, NJ 07936, USA

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First published: April 16, 1996

https://doi.org/10.1002/chin.199616142

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Abstract

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ChemInform Abstract

Starting from the dithioacetals (I) of aromatic aldehydes a general method for the preparation of α-mercapto ketones (VIII) (7 examples) is reported. These are suitable precursors for the synthesis of highly functionalized thiophenes (XII).