Volume 27, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Synthesis of exo-Enynes by Ruthenium-Catalyzed Cross-Coupling Reaction of Hydroxy Allenes and 1-Alkynes.

M. YAMAGUCHI

M. YAMAGUCHI

Dep. Chem., Grad. Sch. Sci., Tohoku Univ., Aoba, Sendai 980-77, Japan

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Y. KIDO

Y. KIDO

Dep. Chem., Grad. Sch. Sci., Tohoku Univ., Aoba, Sendai 980-77, Japan

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K. OMATA

K. OMATA

Dep. Chem., Grad. Sch. Sci., Tohoku Univ., Aoba, Sendai 980-77, Japan

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M. HIRAMA

M. HIRAMA

Dep. Chem., Grad. Sch. Sci., Tohoku Univ., Aoba, Sendai 980-77, Japan

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First published: April 16, 1996

Abstract

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ChemInform Abstract

The cross-coupling reaction of hydroxy allenes with terminal alkynes ( 22 examples) is effectively catalyzed under the optimized conditions A) yielding exo-enynes selectively.

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