Volume 27, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Asymmetric Sulfoxidation Using ((3,3-Dimethoxycamphoryl)sulfonyl) oxaziridine.

P. C. B. PAGE

P. C. B. PAGE

Dep. Chem., Univ. Liverpool, Liverpool L69 3BX, UK

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J. P. HEER

J. P. HEER

Dep. Chem., Univ. Liverpool, Liverpool L69 3BX, UK

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D. BETHELL

D. BETHELL

Dep. Chem., Univ. Liverpool, Liverpool L69 3BX, UK

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E. W. COLLINGTON

E. W. COLLINGTON

Dep. Chem., Univ. Liverpool, Liverpool L69 3BX, UK

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D. M. ANDREWS

D. M. ANDREWS

Dep. Chem., Univ. Liverpool, Liverpool L69 3BX, UK

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First published: April 16, 1996

Abstract

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ChemInform Abstract

The title oxaziridine (SOA) is found to be an efficient agent for asymmetric oxidation of sulfides including dialkyl sulfides. Oxidation in the presence of ((3,3-dimethoxycamphoryl)sulfonyl)imine and H2O2 leads to similar results indicating that the oxaziridine (SOA) is the reactive intermediate.

chemical structure image

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