ChemInform Abstract: Asymmetric Sulfoxidation Using ((3,3-Dimethoxycamphoryl)sulfonyl) oxaziridine.
Abstract
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ChemInform Abstract
The title oxaziridine (SOA) is found to be an efficient agent for asymmetric oxidation of sulfides including dialkyl sulfides. Oxidation in the presence of ((3,3-dimethoxycamphoryl)sulfonyl)imine and H2O2 leads to similar results indicating that the oxaziridine (SOA) is the reactive intermediate.