Volume 27, Issue 11
Organoelement Compounds
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ChemInform Abstract: Phosphorylation of 1,3-Di(N-alkyl)Azoles by Phosphorus(V) Acid Chlorides - A Route to Potential Haptens Derived from Phosphinic Acids.

I. V. KOMAROV

I. V. KOMAROV

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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M. YU. KORNILOV

M. YU. KORNILOV

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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A. V. TUROV

A. V. TUROV

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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M. V. GORICHKO

M. V. GORICHKO

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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V. O. POPOV

V. O. POPOV

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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A. A. TOLMACHEV

A. A. TOLMACHEV

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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A. J. KIRBY

A. J. KIRBY

Dep. Chem., Kiev Taras Shevchenko Univ., Kiev 252017, Ukraine

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First published: March 12, 1996

Abstract

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ChemInform Abstract

Phosphorylation of imidazoles like (I) and (X) by the chlorides (II) followed by amination or hydrolysis leads to phosphinic (phosphonic) amides, acids or their salts. These compounds, especially functionalized derivatives like (IX) and (XI), are useful precursors of haptens such as (XIV).

chemical structure image

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