Volume 27, Issue 11
Preparative Organic Chemistry
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ChemInform Abstract: Reaction of ortho-Phenylenediamines with Electron-Rich Alkenes and Formaldehyde.

J. M. MELLOR

J. M. MELLOR

Dep. Chem., Southampton Univ., Southampton SO17 1BJ, UK

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G. D. MERRIMAN

G. D. MERRIMAN

Dep. Chem., Southampton Univ., Southampton SO17 1BJ, UK

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P. L. MITCHELL

P. L. MITCHELL

Dep. Chem., Southampton Univ., Southampton SO17 1BJ, UK

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First published: March 12, 1996

Abstract

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ChemInform Abstract

The title reaction offers a new simple route to tricyclic benzodiazepines (VI) which are of biological interest. In addition, pentacyclic diamines are formed. In the presence of a large excess of formaldehyde pentacyclic formamides are obtained.

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