ChemInform Abstract: A New Tetradentate Nitrogen Ligand for Organometallic Catalysis: Electrochemical Nickel-Catalyzed Intramolecular Cyclization.
Abstract
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ChemInform Abstract
The new tetraaza-molecule (V) is used as a tetradentate ligand for a cationic mononuclear Ni(II) complex. This complex is an efficient catalyst for the intramolecular electrochemical cyclization of o- haloaryl compounds containing unsaturated side chains as shown.