Volume 26, Issue 19
Natural Products
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ChemInform Abstract: A Simple Cycloaddition Approach to a Racemate of the Natural Sweetener Monatin.

C. W. HOLZAPFEL

C. W. HOLZAPFEL

Dep. Chem., Rand Afr. Univ., Johannesburg, S. Afr.

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K. BISCHOFBERGER

K. BISCHOFBERGER

Dep. Chem., Rand Afr. Univ., Johannesburg, S. Afr.

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J. OLIVIER

J. OLIVIER

Dep. Chem., Rand Afr. Univ., Johannesburg, S. Afr.

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First published: May 9, 1995

Abstract

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ChemInform Abstract

Racemic monatin (IV) is prepared as a mixture of diastereomers, from which the (S,S)/(R,R) isomers can be isolated by selective precipitation. Preliminary attempts to prepare diastereomerically pure monatin with Oppolzer′s sultam are described.

chemical structure image

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