Heterocyclic Compounds
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ChemInform Abstract: Synthetically Useful C-4 Fluorinated Building Blocks Bearing a Quaternary Stereocenter.
First published: May 9, 1995
Abstract
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ChemInform Abstract
The synthesis of homochiral fluorinated oxirane derivatives (cf. (IV), (VII)) based on the Pummerer rearrangement of chiral sulfinyl oxirane ( I) and subsequent epoxide ring opening reactions with selected N- nucleophiles is described.
