Preparative Organic Chemistry
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ChemInform Abstract: The Effects of β-Alkoxy Substituents on Radical Reactions: Halogen Atom Abstraction from Alkyl Chlorides.
First published: May 9, 1995
Abstract
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ChemInform Abstract
The rate of chlorine atom abstraction from (I), (II) and (III) by triethylsilyl or, especially, trimethylamine butylboryl radicals is accelerated by β-alkoxy groups as in (Ia), (IIa) and (IIIa); the cis-isomer (IIa) is 2-3 times more reactive than the trans-isomer ( IIIa).
