Volume 26, Issue 19
Preparative Organic Chemistry
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ChemInform Abstract: A Highly Selective Asymmetric Methoxyselenylation of Alkenes with a Chiral Ferrocenylselenium Reagent.

S. FUKUZAWA

S. FUKUZAWA

Dep. Appl. Chem., Chuo Univ., Bunkyo, Tokyo 112, Japan

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Y. KASUGAHARA

Y. KASUGAHARA

Dep. Appl. Chem., Chuo Univ., Bunkyo, Tokyo 112, Japan

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S. UEMURA

S. UEMURA

Dep. Appl. Chem., Chuo Univ., Bunkyo, Tokyo 112, Japan

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First published: May 9, 1995

Abstract

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ChemInform Abstract

Freshly prepared chiral ferrocenylselenyl bromide (I) and its enantiomer react with alkenes in the presence of methanol according to D) with high facial selectivity to afford selenomethoxylated adducts.

chemical structure image

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