Preparative Organic Chemistry
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ChemInform Abstract: New Chiral 1,1′-Bis(Phospholano)ferrocene Ligands for Asymmetric Catalysis.
First published: May 9, 1995
Abstract
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ChemInform Abstract
Asymmetric catalytic hydrogenation of several model olefin (I), ketone (III) or hydrazone (V) substrates using new 1,1′-bis(phospholano) ferrocene ligands in the Rh(I)-catalyst leads to the corresponding saturated compounds with moderate to good e.e. values. The methyl derivative dpmf is found to be more effective.
