Volume 26, Issue 9
Heterocyclic Compounds
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ChemInform Abstract: Reactivity of 1-Aza-1,4,5,6-tetrahydroazulenes and Their Utility in the Preparation of Dipyrrolic Intermediates Needed for Petroporphyrin Synthesis.

T. D. LASH

T. D. LASH

Dep. Chem., Illinois State Univ., Normal, IL 61790-4160, USA

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T. H. NGUYEN

T. H. NGUYEN

Dep. Chem., Illinois State Univ., Normal, IL 61790-4160, USA

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Z. HU

Z. HU

Dep. Chem., Illinois State Univ., Normal, IL 61790-4160, USA

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First published: February 28, 1995

Abstract

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ChemInform Abstract

The azatetrahydroazulene (VIa) prepared from cycloheptanone (I) via the labile acetate (Va) undergoes coupling reaction with the pyrrole methanols (VII) under acidic conditions to yield the petroporphyrin synthons (VIII).

chemical structure image

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