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ChemInform Abstract: First Synthesis of the Novel Gelsemium Alkaloids, Gelselegine (V), Gelsenicine (VI), and Gelsedine (VII) Using a Biomimetic Approach.
First published: February 7, 1995
Abstract
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ChemInform Abstract
The synthesis of the title compounds starts with (19E)-koumidine (I), readily available from the Gardneria indole alkaloid gardnerine, and includes a series of stereoselective skeletal rearrangements.
