Volume 26, Issue 6
Organoelement Compounds
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ChemInform Abstract: 1-Aza-1,3-bis(triphenylphosphoranylidene)propane: A Novel =CHCH2N= Synthon.

A. R. KATRITZKY

A. R. KATRITZKY

Dep. Chem., Univ. Fla., Gainesville, FL 32611-7200, USA

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J. JIANG

J. JIANG

Dep. Chem., Univ. Fla., Gainesville, FL 32611-7200, USA

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P. J. STEEL

P. J. STEEL

Dep. Chem., Univ. Fla., Gainesville, FL 32611-7200, USA

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First published: February 7, 1995

Abstract

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ChemInform Abstract

The title compound (III), already reported in a preliminary paper, is prepared in situ and is stable in THF below -20 °C under argon or nitrogen. A suspension of (III) is used directly in the reactions shown in the scheme and enables convenient preparations of diarylpyrroles of type (VII) and primary allylamines (cf. (XIV), (XV) and (XVII)).

chemical structure image

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