Preparative Organic Chemistry
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ChemInform Abstract: Photo-Induced Reactions of Organic Compounds with Metal Complexes. Part 28. Photooxidation of Cyclohexane with Air in Acetonitrile Catalyzed by π Complexes of Iron.
First published: March 29, 1994
Abstract
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ChemInform Abstract
Fe(II)-π complexes, without chlorine ligands, efficiently catalyze the photooxidation of cyclohexane in MeCN to furnish the corresponding hydroperoxide and its decomposition products. Kinetic and mechanistic considerations of this oxidation process are discussed.
