Isocyclic Compounds
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ChemInform Abstract: High Reactivity of Heterocoerdianthrones (HCDs) in Photoperoxidation and Thermal Stability of Their Endoperoxides. Use of HCD as a Photosensitizer Under Sunlight.
First published: August 10, 1993
Abstract
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ChemInform Abstract
The title compounds (III) show a high reactivity towards singlet oxygen which is due to their strained structure. The large thermal stability of the endoperoxides (IV) is also explained by considering the strained structure of (III). As a prospect of solar synthesis ( IIIb) is used as a photosensitizer for singlet-oxygen oxidation of . alpha.-terpinene.
