Volume 24, Issue 32
Isocyclic Compounds
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ChemInform Abstract: Reaction of α- and β-Methoxystyrenes with Arylsulfonyl Azides.

V. P. SEMENOV

V. P. SEMENOV

S.-Peterb. gos. univ., St.-Petersburg, Russia

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First published: August 10, 1993

Abstract

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ChemInform Abstract

The title reactions furnish imidates (IV) or (VII), resp., (8 examples in all) resulting from cleavage of initially formed triazoline intermediates such as (III) with elimination of N2 and 1,2-migration of the phenyl group. Hydrolysis of imidate (IVc) in acidic media gives the propanoic acid (V).

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